The Inside Cover picture schematically illustrates visible‐light‐driven, single‐photocatalyst‐promoted photocascade catalysis. Recent examples of photocascade catalytic transformations are categorised by the activation modes of substrates and intermediates involved in these processes. More information can be found in the Concept Article by W.‐J. Xiao and co‐workers on page 148 in Issue 5, 2017 (DOI:10.1002/cptc.201700008).